Teaching Modules

REACTION INTERMEDIATES: HALONIUM IONS > STEPS REQUIRED > Search for evidence, in the Cambridge Structural Database, that the cyclic bromonium ion actually does exist.
Search for evidence, in the Cambridge Structural Database, that the cyclic bromonium ion actually does exist.
Start ConQuest and hit the Draw button to open the Draw window.
Sketch the cyclic bromonium ion shown below. Remember to specify a charge of +1 on the bromine. This can be done, e.g. by right-clicking on the Br atom at selecting Charge, followed by Positive and then +1 from the resulting pull-down menus.
Hit Search, then in the Search Setup window hit Start Search.
As soon as you start the search, the ConQuest interface moves to the View Results pane. After a few moments, the refcodes of any hit structures will appear in the list on the right-hand side.
You should retrieve two hits (refcodes DAKVUG and WEVPIW). Both are examples of adamantylidene-adamantane-bromonium ions. Examine these two structures.